An evaluation of ligand properties of neutral and anionic tris(imidazol-2-yl)phosphines
In order to study the applicability of tris(imidazol-2-yl)phosphine (PIm3) as a possible charge-variable ligand, new neutral N-butyl and N-benzyl derivatives and d0-metal complexes thereof were prepared and characterized as reference compounds for planned complexes with high valent metals. In additi...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
2004
|
| In: |
Zeitschrift für anorganische und allgemeine Chemie
Year: 2004, Volume: 630, Issue: 10, Pages: 1501-1506 |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.200400149 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.200400149 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200400149 |
| Author Notes: | Markus Enders, Olaf Fritz, Hans Pritzkow |
| Summary: | In order to study the applicability of tris(imidazol-2-yl)phosphine (PIm3) as a possible charge-variable ligand, new neutral N-butyl and N-benzyl derivatives and d0-metal complexes thereof were prepared and characterized as reference compounds for planned complexes with high valent metals. In addition, an anionic ligand precursor was characterized by X-Ray analysis and its reactivity towards transition metal halides assayed. |
|---|---|
| Item Description: | First published: 23 August 2004 Gesehen am 18.11.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.200400149 |