Cover Image

Synthesis of a stable B2H5+ analogue by protonation of a double base-stabilized diborane(4)

Polarity of H+ reversed: The synthesis of [B2H3(hpp)2]+I−,a dinuclear borohydride with terminal and bridging H atoms (see picture; B yellow, N blue, C gray, H white, I purple), is made possible with the ligand hexahydropyrimidopyrimidate (hpp). In the course of the reaction the proton is converted i...

Full description

Saved in:
Bibliographic Details
Main Authors: Ciobanu, Oxana (Author) , Kaifer, Elisabeth (Author) , Enders, Markus (Author) , Himmel, Hans-Jörg (Author)
Format: Article (Journal)
Language:English
Published: 2009
In: Angewandte Chemie. International edition
Year: 2009, Volume: 48, Issue: 30, Pages: 5538-5541
ISSN:1521-3773
DOI:10.1002/anie.200901842
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200901842
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200901842
Get full text
Author Notes:Oxana Ciobanu, Elisabeth Kaifer, Markus Enders, and Hans-Jörg Himmel
Description
Summary:Polarity of H+ reversed: The synthesis of [B2H3(hpp)2]+I−,a dinuclear borohydride with terminal and bridging H atoms (see picture; B yellow, N blue, C gray, H white, I purple), is made possible with the ligand hexahydropyrimidopyrimidate (hpp). In the course of the reaction the proton is converted into a hydride.
Item Description:Im Titel sind "2" und "5" tiefgestellt, "+" hochgestellt
First published: 08 July 2009
Gesehen am 29.11.2022
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200901842

Similar Items