An efficient synthesis of tetraazapentacenes
Organic electronics on demand? The palladium-catalyzed coupling of aromatic ortho-diamines with substituted dichloroquinoxalines furnishes N,N-dihydrotetraazaacenes, which were oxidized by MnO2 into the corresponding tetraazapentacenes (see structures; N blue, Cl green, Si yellow). The modular synth...
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| Main Authors: | , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
17 March 2011
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| In: |
Angewandte Chemie. International edition
Year: 2011, Volume: 50, Issue: 15, Pages: 3557-3560 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201007654 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201007654 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201007654 |
| Author Notes: | Olena Tverskoy, Frank Rominger, Anastasia Peters, Hans-Jörg Himmel and Uwe H.F. Bunz |
| Summary: | Organic electronics on demand? The palladium-catalyzed coupling of aromatic ortho-diamines with substituted dichloroquinoxalines furnishes N,N-dihydrotetraazaacenes, which were oxidized by MnO2 into the corresponding tetraazapentacenes (see structures; N blue, Cl green, Si yellow). The modular synthesis of these acenes allows the introduction of any substituent by choice of the proper quinoxaline derivative. |
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| Item Description: | Dedicated to Professor Günter Helmchen and Professor Rolf Gleiter Gesehen am 30.11.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201007654 |