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Fusion of a 1,3-diboraruthenocene to form a slipped μ-hexahydrotetraboranaphthalene triple-decker complex with two axial C-H bonds$3hElena V. Mutseneck, Hubert Wadepohl, Markus Enders, Alexander R. Kudinov, and Walter Siebert

Colliding double deckers: Addition of zinc to a reaction mixture of [Cp*RuCl4]/pentamethyl-2,3-dihydro-1,3-diborole (C3B2Me5H) in THF leads to three known double- and triple-decker complexes of [C3B2Me5]−, and unexpectedly to the slipped triple-decker (see picture) with two fused diborole rings. The...

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Bibliographic Details
Main Authors: Mutseneck, Elena V. (Author) , Wadepohl, Hubert (Author) , Enders, Markus (Author) , Kudinov, Alexander R. (Author) , Siebert, Walter (Author)
Format: Article (Journal)
Language:English
Published: 2009
In: Angewandte Chemie. International edition
Year: 2009, Volume: 48, Issue: 8, Pages: 1429-1431
ISSN:1521-3773
DOI:10.1002/anie.200802945
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200802945
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200802945
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Summary:Colliding double deckers: Addition of zinc to a reaction mixture of [Cp*RuCl4]/pentamethyl-2,3-dihydro-1,3-diborole (C3B2Me5H) in THF leads to three known double- and triple-decker complexes of [C3B2Me5]−, and unexpectedly to the slipped triple-decker (see picture) with two fused diborole rings. The endo CH bonds of two MeCH groups donate two additional electrons to achieve the stable 34 VE configuration.
Item Description:μ mu
First published: 30 January 2009
Gesehen am 30.11.2022
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200802945

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