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Metal silylenes generated by double silicon-hydrogen activation: key intermediates in the rhodium-catalyzed hydrosilylation of ketones : dedicated to Professor Helmut Werner on the occasion of his 75th birthday

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Rhodium silylenes, which are generated by double Si-H activation at the metal, are involved in a low-activation-barrier mechanism of the hydrosilylation of ketones with R2SiH2. A DFT-based study of reaction mechanisms accounts for the experimental observations, notably the rate enhancement for R2SiH...

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Main Authors: Schneider, Nathanaëlle (Author) , Finger, Markus (Author) , Haferkemper, Christian (Author) , Bellemin-Laponnaz, Stéphane (Author) , Hofmann, Peter (Author) , Gade, Lutz H. (Author)
Format: Article (Journal) Festschrift
Language:English
Published: 2009
In: Angewandte Chemie. International edition
Year: 2009, Volume: 48, Issue: 9, Pages: 1609-1613
ISSN:1521-3773
DOI:10.1002/anie.200804993
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Festschrift
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200804993
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200804993
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Author Notes:Nathanaëlle Schneider, Markus Finger, Christian Haferkemper, Stéphane Bellemin-Laponnaz, Peter Hofmann, and Lutz H. Gade
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Summary:Rhodium silylenes, which are generated by double Si-H activation at the metal, are involved in a low-activation-barrier mechanism of the hydrosilylation of ketones with R2SiH2. A DFT-based study of reaction mechanisms accounts for the experimental observations, notably the rate enhancement for R2SiH2 over R3SiH and an inverse kinetic isotope effect.
Item Description:First published: 10 February 2009
Gesehen am 07.12.2022
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200804993

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