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Allylic peroxidations with bis(2-pyridylimino)isoindolato-cobalt and -iron complexes: dedicated to Professor Michael Veith on the occasion of his 60th birthday

Several novel substituted bis(2-pyridylimino)isoindolato (BPI) cobalt(II) and iron(II) complexes [M(BPI)(OAc)(H2O)] (M = Co: 1 - 6, Fe: 7) have been synthesized by reaction of bis(2-pyridylimino)isoindole derivatives with the corresponding metal(II) acetates. Reaction of 1-6 with 1.5 - 2 molar equiv...

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Bibliographic Details
Main Authors: Meder, Markus B. (Author) , Siggelkow, Bettina A. (Author) , Gade, Lutz H. (Author)
Format: Article (Journal) Festschrift
Language:English
Published: 2004
In: Zeitschrift für anorganische und allgemeine Chemie
Year: 2004, Volume: 630, Issue: 12, Pages: 1962-1968
ISSN:1521-3749
DOI:10.1002/zaac.200400253
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Festschrift
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.200400253
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200400253
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Author Notes:Markus B. Meder, Bettina A. Siggelkow, and Lutz H. Gade
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Summary:Several novel substituted bis(2-pyridylimino)isoindolato (BPI) cobalt(II) and iron(II) complexes [M(BPI)(OAc)(H2O)] (M = Co: 1 - 6, Fe: 7) have been synthesized by reaction of bis(2-pyridylimino)isoindole derivatives with the corresponding metal(II) acetates. Reaction of 1-6 with 1.5 - 2 molar equivalents of t-BuOOH gave the corresponding alkylperoxocobalt(III) complexes [Co(BPI)(OAc)(OOtBu)] (10 - 15). Using an aqueous solution of t-BuOOH (70 %), cyclohexene was selectively catalytically oxidized to the dialkylperoxide cyclohex-2-ene-1-t-butylperoxide.
Item Description:First published: 21 October 2004
Gesehen am 13.12.2022
Physical Description:Online Resource
ISSN:1521-3749
DOI:10.1002/zaac.200400253

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