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Self-assembly of a cyclic Zn4O4 tetramer by aerobic oxidation of a bisoxazoline: a molecular "Nest" for nucleophilic OH-

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Nesting hydroxide: Coordination and aerobic oxidation of a bisoxazoline Me2box is coupled with self-assembly to form a highly ordered [(Me2box)O4Zn4]4+ complex. The metallamacrocycle acts as a nest-like hydroxide receptor (see scheme, right) and shows catalytic phosphatase activity.

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Bibliographic Details
Main Authors: Jacques, Béatrice (Author) , Dro, Clémence (Author) , Bellemin-Laponnaz, Stéphane (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 27 May 2008
In: Angewandte Chemie. International edition
Year: 2008, Volume: 47, Issue: 24, Pages: 4546-4550
ISSN:1521-3773
DOI:10.1002/anie.200800870
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200800870
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200800870
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Author Notes:Béatrice Jacques, Clémence Dro, Stéphane Bellemin-Laponnaz, Hubert Wadepohl, and Lutz H. Gade
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Summary:Nesting hydroxide: Coordination and aerobic oxidation of a bisoxazoline Me2box is coupled with self-assembly to form a highly ordered [(Me2box)O4Zn4]4+ complex. The metallamacrocycle acts as a nest-like hydroxide receptor (see scheme, right) and shows catalytic phosphatase activity.
Item Description:Im Titel ist die Zahl 4 jeweils tiefgestellt
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Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200800870

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