Self-assembly of a cyclic Zn4O4 tetramer by aerobic oxidation of a bisoxazoline: a molecular "Nest" for nucleophilic OH-
Nesting hydroxide: Coordination and aerobic oxidation of a bisoxazoline Me2box is coupled with self-assembly to form a highly ordered [(Me2box)O4Zn4]4+ complex. The metallamacrocycle acts as a nest-like hydroxide receptor (see scheme, right) and shows catalytic phosphatase activity.
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
27 May 2008
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| In: |
Angewandte Chemie. International edition
Year: 2008, Jahrgang: 47, Heft: 24, Pages: 4546-4550 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200800870 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200800870 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200800870 
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| Verfasserangaben: | Béatrice Jacques, Clémence Dro, Stéphane Bellemin-Laponnaz, Hubert Wadepohl, and Lutz H. Gade |
| Zusammenfassung: | Nesting hydroxide: Coordination and aerobic oxidation of a bisoxazoline Me2box is coupled with self-assembly to form a highly ordered [(Me2box)O4Zn4]4+ complex. The metallamacrocycle acts as a nest-like hydroxide receptor (see scheme, right) and shows catalytic phosphatase activity. |
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| Beschreibung: | Im Titel ist die Zahl 4 jeweils tiefgestellt Gesehen am 14.12.2022 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200800870 |