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A zirconium hydrazide as a synthon for a metallanitrene equivalent: atom-by-atom assembly of (EN2)2- units (E=S, Se) by chalcogen-atom transfer in the coordination sphere of a transition metal

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Piece by piece: Hydrazides at zirconium centers undergo facile NN bond cleavage and react as equivalents for metallanitrenes, thus allowing the atom-by-atom assembly of bridging dinitridosulfate(IV) and dinitridoselenate(IV) ligands (see scheme; TBS=tBuMe2Si).

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Bibliographic Details
Main Authors: Herrmann, Heike (Author) , Lloret Fillol, Julio (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 02 November 2007
In: Angewandte Chemie. International edition
Year: 2007, Volume: 46, Issue: 44, Pages: 8426-8430
ISSN:1521-3773
DOI:10.1002/anie.200703938
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200703938
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200703938
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Author Notes:Heike Herrmann, Julio Lloret Fillol, Hubert Wadepohl, and Lutz H. Gade
Description
Summary:Piece by piece: Hydrazides at zirconium centers undergo facile NN bond cleavage and react as equivalents for metallanitrenes, thus allowing the atom-by-atom assembly of bridging dinitridosulfate(IV) and dinitridoselenate(IV) ligands (see scheme; TBS=tBuMe2Si).
Item Description:Gesehen am 16.12.2022
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200703938

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