Identification of di-o,o′-Cl-, mono-o-Cl- and non-o-Cl-substituted PCB congeners in Neckar river fish

Di-o,o′-Cl-, mono-o-Cl- and the highly toxic non-o-Cl-substituted PCBs could be found in muscle tissue of the six different fish species eel, perch, roach, chub, bleak and barbel. The PCBs were identified by GC/ECD and GC/MS. The measured PCB concentrations were transformed in TEQ-values for better...

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Bibliographic Details
Main Authors: Haiber, Georg (Author) , Schöler, Heinz Friedrich (Author)
Format: Article (Journal)
Language:English
Published: 1994
In: Chemosphere
Year: 1994, Volume: 28, Issue: 11, Pages: 1913-1919
ISSN:1879-1298
DOI:10.1016/0045-6535(94)90142-2
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/0045-6535(94)90142-2
Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/0045653594901422
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Author Notes:G. Haiber, H.F. Schöler
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Summary:Di-o,o′-Cl-, mono-o-Cl- and the highly toxic non-o-Cl-substituted PCBs could be found in muscle tissue of the six different fish species eel, perch, roach, chub, bleak and barbel. The PCBs were identified by GC/ECD and GC/MS. The measured PCB concentrations were transformed in TEQ-values for better risk assessment. In eel the average PCB concentration (the sum of the congeners # 28, 52, 101, 138, 153, 180) is 423 μg/kg and 0.36 TEQ/kg for mono-o-Cl- and coplanar PCBs. Because of the fat content in eel the average PCB contamination is about four times higher than in the other fish. None of the PCB values for # 28, 52, 101, 138, 153 and 180 exceed the German maximum acceptable residue limits for food (SHmV) though the toxic PCB # 77, 126 and 169 are not taken into consideration.
Item Description:Elektronische Reproduktion der Druck-Ausgabe 26. März 2003
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Physical Description:Online Resource
ISSN:1879-1298
DOI:10.1016/0045-6535(94)90142-2