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Determination of the conformation of the key intermediate in an enantioselective palladium-catalyzed allylic substitution from residual dipolar couplings

Hide and seek! The reactive intermediate in the title reaction has eluded conventional structure determination for years. With the help of residual dipolar couplings the conformation in solution could be determined (see picture). The sensitive intermediate was aligned in a liquid-crystalline phase c...

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Bibliographic Details
Main Authors: Böttcher, Benjamin (Author) , Schmidts, Volker (Author) , Raskatov, Jevgenij (Author) , Thiele, Christina M. (Author)
Format: Article (Journal)
Language:English
Published: 2010
In: Angewandte Chemie. International edition
Year: 2010, Volume: 49, Issue: 1, Pages: 205-209
ISSN:1521-3773
DOI:10.1002/anie.200903649
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200903649
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200903649
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Author Notes:Benjamin Böttcher, Volker Schmidts, Jevgenij A. Raskatov, and Christina M. Thiele
Description
Summary:Hide and seek! The reactive intermediate in the title reaction has eluded conventional structure determination for years. With the help of residual dipolar couplings the conformation in solution could be determined (see picture). The sensitive intermediate was aligned in a liquid-crystalline phase containing poly(γ-benzyl-L-glutamate), and the orientation of the ligands was determined through local order tensors.
Item Description:Erstmals am 22. Dezember 2009 online veröffentlicht
Gesehen am 01.02.2023
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200903649

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