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Bridging N-aminoisocyanate ligands in heterobimetallic complexes: coupling of zirconium hydrazinediides and transition-metal carbonyls

Reaction of the zirconium complex [Zr(N2TBSNpy)(═NNPh2)(py)] with metal carbonyl complexes yielded the heteronuclear complexes [(N2TBSNpy)(py)Zr{μ-OCNNPh2-1κC:2κ2NO}Mm(CO)n] (M = Cr, Mo, W (m = 1, n = 5), Fe (m = 1, n = 4), Mn (m = 2, n = 9)). The bridging N-aminoisocyanato ligands in the dinuclear...

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Bibliographic Details
Main Authors: Gehrmann, Thorsten (Author) , Lloret Fillol, Julio (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 2010
In: Organometallics
Year: 2010, Volume: 29, Issue: 1, Pages: 28-31
ISSN:1520-6041
DOI:10.1021/om900877c
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om900877c
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Author Notes:Thorsten Gehrmann, Julio Lloret Fillol, Hubert Wadepohl, and Lutz H. Gade
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Summary:Reaction of the zirconium complex [Zr(N2TBSNpy)(═NNPh2)(py)] with metal carbonyl complexes yielded the heteronuclear complexes [(N2TBSNpy)(py)Zr{μ-OCNNPh2-1κC:2κ2NO}Mm(CO)n] (M = Cr, Mo, W (m = 1, n = 5), Fe (m = 1, n = 4), Mn (m = 2, n = 9)). The bridging N-aminoisocyanato ligands in the dinuclear complexes were formed by [2 + 2] cycloaddition of the Zr═NNR2 unit and coordinated CO.
Item Description:Received October 9, 2009
Gesehen am 22.02.2023
Physical Description:Online Resource
ISSN:1520-6041
DOI:10.1021/om900877c

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