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Electron-transfer properties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine ligand

The oxidation catalyst [(L)FeIVO] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a FeIVO species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the o...

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Bibliographic Details
Main Authors: Comba, Peter (Author) , Fukuzumi, Shunichi (Author) , Kotani, Hiroaki (Author) , Wunderlich, Steffen (Author)
Format: Article (Journal)
Language:English
Published: March 12, 2010
In: Angewandte Chemie. International edition
Year: 2010, Volume: 49, Issue: 14, Pages: 2622-2625
ISSN:1521-3773
DOI:10.1002/anie.200904427
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200904427
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200904427
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Author Notes:Peter Comba, Shunichi Fukuzumi, Hiroaki Kotani, and Steffen Wunderlich
Description
Summary:The oxidation catalyst [(L)FeIVO] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a FeIVO species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the organic substrates.
Item Description:Gesehen am 26.05.2023
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200904427

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