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Platinum(II) chloride-catalyzed stereoselective domino enyne isomerization/Diels-Alder reaction

Chiral 1,6-enynes were prepared via Ir-catalyzed allylic substitutions. Their platinum(II) chloride-catalyzed domino enyne isomerization/Diels−Alder reaction provided stereoselective access to complex heterocycles. Very high diastereoselectivity was induced by a chirality center of the enyne.

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Bibliographic Details
Main Authors: Schelwies, Mathias (Author) , Farwick, Andreas (Author) , Rominger, Frank (Author) , Helmchen, Günter (Author)
Format: Article (Journal)
Language:English
Published: October 19, 2010
In: The journal of organic chemistry
Year: 2010, Volume: 75, Issue: 22, Pages: 7917-7919
ISSN:1520-6904
DOI:10.1021/jo1014068
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/jo1014068
Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/jo1014068
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Author Notes:Mathias Schelwies, Andreas Farwick, Frank Rominger, and Günter Helmchen
Description
Summary:Chiral 1,6-enynes were prepared via Ir-catalyzed allylic substitutions. Their platinum(II) chloride-catalyzed domino enyne isomerization/Diels−Alder reaction provided stereoselective access to complex heterocycles. Very high diastereoselectivity was induced by a chirality center of the enyne.
Item Description:Gesehen am 01.06.2023
Physical Description:Online Resource
ISSN:1520-6904
DOI:10.1021/jo1014068

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