Platinum(II) chloride-catalyzed stereoselective domino enyne isomerization/Diels-Alder reaction
Chiral 1,6-enynes were prepared via Ir-catalyzed allylic substitutions. Their platinum(II) chloride-catalyzed domino enyne isomerization/Diels−Alder reaction provided stereoselective access to complex heterocycles. Very high diastereoselectivity was induced by a chirality center of the enyne.
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
October 19, 2010
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| In: |
The journal of organic chemistry
Year: 2010, Jahrgang: 75, Heft: 22, Pages: 7917-7919 |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/jo1014068 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/jo1014068 Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/jo1014068 
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| Verfasserangaben: | Mathias Schelwies, Andreas Farwick, Frank Rominger, and Günter Helmchen |
| Zusammenfassung: | Chiral 1,6-enynes were prepared via Ir-catalyzed allylic substitutions. Their platinum(II) chloride-catalyzed domino enyne isomerization/Diels−Alder reaction provided stereoselective access to complex heterocycles. Very high diastereoselectivity was induced by a chirality center of the enyne. |
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| Beschreibung: | Gesehen am 01.06.2023 |
| Beschreibung: | Online Resource |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/jo1014068 |