μ3-Oxido-tris{dichlorido[1,3-bis(1,3,5-trimethylphenyl)imidazol-2-ylidene]gold(III)} bis(trifluoromethanesulfonyl)imide-[bis(trifluoromethanesulfonyl)imide]silver(I) (1/2)
The unusual trinuclear AuIII oxide title complex, [Au3Cl6O(C21H24N2)3](C2F6NO4S2)·2[Ag(C2F6NO4S2)], is the side product of the reaction of [1,3-bis(1,3,5-trimethylphenyl)imidazol-2-ylidene]dichloridophenylgold(III) with silver bis(trifluoromethanesulfonyl)imide in the presence of traces of...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
5 June 2010
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| In: |
Acta crystallographica. Section E, Structure reports online
Year: 2010, Volume: 66, Issue: 7, Pages: m724-m725 |
| ISSN: | 1600-5368 |
| DOI: | 10.1107/S160053681001994X |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1107/S160053681001994X Verlag, lizenzpflichtig, Volltext: https://scripts.iucr.org/cgi-bin/paper?hg2690 
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| Author Notes: | Marek Pažický, Frank Rominger and Michael Limbach |
| Summary: | The unusual trinuclear AuIII oxide title complex, [Au3Cl6O(C21H24N2)3](C2F6NO4S2)·2[Ag(C2F6NO4S2)], is the side product of the reaction of [1,3-bis(1,3,5-trimethylphenyl)imidazol-2-ylidene]dichloridophenylgold(III) with silver bis(trifluoromethanesulfonyl)imide in the presence of traces of water. In contrast to corresponding AuI complexes, the core structure of the title compound is planar. Two silver(I) bis(trifluoromethanesulfonyl)imide units are loosely bound to the complex cation. Here the silver atoms, disordered over two positions in a 0.870 (2):0.130 (2) ratio, interact either with the lone pairs of three chlorine ligands or two chlorine ligands and one edge of the mesityl π-system. The crystal under investigation was a partial racemic twin. |
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| Item Description: | Im Text ist "3" tiefgestellt Gesehen am 30.06.2023 |
| Physical Description: | Online Resource |
| ISSN: | 1600-5368 |
| DOI: | 10.1107/S160053681001994X |