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Single crystals of insoluble porous salicylimine cages [data]

Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorp...

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Main Authors: Holsten, Mattes (Author) , Elbert, Sven (Author) , Rominger, Frank (Author) , Zhang, Wen-Shan (Author) , Schröder, Rasmus R. (Author) , Mastalerz, Michael (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2023-08-23
DOI:10.11588/data/45FZRY
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Forschungsdaten
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Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/45FZRY
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/45FZRY
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Author Notes:Mattes Holsten, Sven Michael Elbert, Frank Rominger, Wen-Shan Zhang, Rasmus R. Schröder, Michael Mastalerz
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Summary:Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorphous materials. These cages were now synthesized as single-crystalline materials to get insight into packing motifs and preferred intermolecular interactions. Furthermore, the pairs of crystalline and amorphous materials for each cage allowed to compare their gas-sorption properties in both morphological states.
Item Description:Gesehen am 24.08.2023
Physical Description:Online Resource
DOI:10.11588/data/45FZRY

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