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Single crystals of insoluble porous salicylimine cages

Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorp...

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Bibliographic Details
Main Authors: Holsten, Mattes (Author) , Elbert, Sven (Author) , Rominger, Frank (Author) , Zhang, Wen-Shan (Author) , Schröder, Rasmus R. (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: November 24, 2023
In: Chemistry - a European journal
Year: 2023, Volume: 29, Issue: 66, Pages: 1-10
ISSN:1521-3765
DOI:10.1002/chem.202302116
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202302116
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202302116
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Author Notes:Mattes Holsten, Sven M. Elbert, Frank Rominger, Wen-Shan Zhang, Rasmus R. Schröder, and Michael Mastalerz
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Summary:Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorphous materials. These cages were now synthesized as single-crystalline materials to get insight into packing motifs and preferred intermolecular interactions. Furthermore, the pairs of crystalline and amorphous materials for each cage allowed to compare their gas-sorption properties in both morphological states.
Item Description:Zuerst online veröffentlicht: 14 August 2023
Gesehen am 15.12.2023
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.202302116

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