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Single crystals of insoluble porous salicylimine cages

Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorp...

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Hauptverfasser: Holsten, Mattes (VerfasserIn) , Elbert, Sven (VerfasserIn) , Rominger, Frank (VerfasserIn) , Zhang, Wen-Shan (VerfasserIn) , Schröder, Rasmus R. (VerfasserIn) , Mastalerz, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: November 24, 2023
In: Chemistry - a European journal
Year: 2023, Jahrgang: 29, Heft: 66, Pages: 1-10
ISSN:1521-3765
DOI:10.1002/chem.202302116
Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202302116
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202302116
Volltext
Verfasserangaben:Mattes Holsten, Sven M. Elbert, Frank Rominger, Wen-Shan Zhang, Rasmus R. Schröder, and Michael Mastalerz
Beschreibung
Zusammenfassung:Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorphous materials. These cages were now synthesized as single-crystalline materials to get insight into packing motifs and preferred intermolecular interactions. Furthermore, the pairs of crystalline and amorphous materials for each cage allowed to compare their gas-sorption properties in both morphological states.
Beschreibung:Zuerst online veröffentlicht: 14 August 2023
Gesehen am 15.12.2023
Beschreibung:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.202302116

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