Cover Image

Solvent-controlled quadruple catenation of giant chiral (8+12) salicylimine cubes driven by weak hydrogen bonding [data]

A quadruply interlocked catenane has been formed from giant chiral [8+12] salicylimine cubes in a reaction that can be controlled by the reaction solvent. Single-crystal X-ray diffraction revealed hydrogen bonding to be a central driving force for the catenation. Furthermore, scrambling experiments...

Full description

Saved in:
Bibliographic Details
Main Authors: Wagner, Philippe (Author) , Rominger, Frank (Author) , Gross, Jürgen H. (Author) , Mastalerz, Michael (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2023-08-23
DOI:10.11588/data/TIYBD2
Subjects:
Forschungsdaten
Datenbank
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/TIYBD2
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/TIYBD2
Get full text
Author Notes:Philippe Wagner, Frank Rominger, Jürgen H. Gross, Michael Mastalerz
Description
Summary:A quadruply interlocked catenane has been formed from giant chiral [8+12] salicylimine cubes in a reaction that can be controlled by the reaction solvent. Single-crystal X-ray diffraction revealed hydrogen bonding to be a central driving force for the catenation. Furthermore, scrambling experiments with partially deuterated cages allowed mechanistic insights into the interlocking process.
Item Description:Im Titel steht der Ausdruck (8+12) in eckiger Klammer
Gesehen am 24.08.2023
Physical Description:Online Resource
DOI:10.11588/data/TIYBD2

Similar Items