Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes [data]

By palladium-catalyzed oligomerization reactions of pyrene-based o-trimethylsilyl triflates, larger cyclic pyrenylenes were formed with up to 10-membered rings as has been unambiguously characterized by SCXRD. Furthermore, the underlying reaction mechanism has been studied by quantum chemical calcul...

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Bibliographic Details
Main Authors: Popp, Dennis (Author) , Elbert, Sven (Author) , Barwig, Chantal (Author) , Petry, Julian (Author) , Rominger, Frank (Author) , Mastalerz, Michael (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2023-08-23
DOI:10.11588/data/1TCKKG
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Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/1TCKKG
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/1TCKKG
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Author Notes:Dennis Popp, Sven Michael Elbert, Chantal Barwig, Julian Petry, Frank Rominger, Michael Mastalerz
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Summary:By palladium-catalyzed oligomerization reactions of pyrene-based o-trimethylsilyl triflates, larger cyclic pyrenylenes were formed with up to 10-membered rings as has been unambiguously characterized by SCXRD. Furthermore, the underlying reaction mechanism has been studied by quantum chemical calculations.
Item Description:Gesehen am 24.08.2023
Physical Description:Online Resource
DOI:10.11588/data/1TCKKG