Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes [data]
By palladium-catalyzed oligomerization reactions of pyrene-based o-trimethylsilyl triflates, larger cyclic pyrenylenes were formed with up to 10-membered rings as has been unambiguously characterized by SCXRD. Furthermore, the underlying reaction mechanism has been studied by quantum chemical calcul...
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| Main Authors: | , , , , , |
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| Format: | Database Research Data |
| Language: | English |
| Published: |
Heidelberg
Universität
2023-08-23
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| DOI: | 10.11588/data/1TCKKG |
| Subjects: | |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/1TCKKG Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/1TCKKG |
| Author Notes: | Dennis Popp, Sven Michael Elbert, Chantal Barwig, Julian Petry, Frank Rominger, Michael Mastalerz |
| Summary: | By palladium-catalyzed oligomerization reactions of pyrene-based o-trimethylsilyl triflates, larger cyclic pyrenylenes were formed with up to 10-membered rings as has been unambiguously characterized by SCXRD. Furthermore, the underlying reaction mechanism has been studied by quantum chemical calculations. |
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| Item Description: | Gesehen am 24.08.2023 |
| Physical Description: | Online Resource |
| DOI: | 10.11588/data/1TCKKG |