Zipping up tetraazaperylene: synthesis of tetraazacoronenes via double coupling in the bay positions
Substituted tetraazacoronene fluorophores have been obtained selectively by double Suzuki-Miyaura cross coupling of symmetrically substituted 1,2-bis(pinacolatoboryl)alkenes with a bay-substituted octaazaperopyrenedioxide (OAPPDO). Subsequent Scholl reaction of the dimethoxyphenylated derivative all...
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| Autores principales: | , , , |
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| Formato: | Article (Journal) |
| Lenguaje: | inglés |
| Publicado: |
18 September 2023
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| In: |
Chemical communications
Year: 2023, Volumen: 59, Número: 81, Pages: 12136-12139 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D3CC04113A |
| Acceso en línea: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D3CC04113A Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2023/cc/d3cc04113a 
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| Notas de Autor: | Robert Eichelmann, Daniel Rippel, Joachim Ballmann and Lutz H. Gade |
| Sumario: | Substituted tetraazacoronene fluorophores have been obtained selectively by double Suzuki-Miyaura cross coupling of symmetrically substituted 1,2-bis(pinacolatoboryl)alkenes with a bay-substituted octaazaperopyrenedioxide (OAPPDO). Subsequent Scholl reaction of the dimethoxyphenylated derivative allowed further π-extension of the azaperylene core, yielding a highly redox-active bis(phenanthro)tetraazacoronene. |
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| Notas: | Gesehen am 24.10.2023 |
| Descripción Física: | Online Resource |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D3CC04113A |