Resolving vibrations in a polyatomic molecule with femtometer precision via x-ray spectroscopy
We measure molecular vibrations with femtometer precision via resonance energy shifts using time-resolved x-ray absorption spectroscopy. For a demonstration, a Raman process excites the A1g mode in gas-phase SF6 molecules with an amplitude of approximately 50fm, which is probed by a time-delayed sof...
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| Main Authors: | , , , , , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
27 September 2023
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| In: |
Physical review
Year: 2023, Volume: 108, Issue: 3, Pages: 1-7 |
| ISSN: | 2469-9934 |
| DOI: | 10.1103/PhysRevA.108.032816 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1103/PhysRevA.108.032816 Verlag, kostenfrei, Volltext: https://link.aps.org/doi/10.1103/PhysRevA.108.032816 
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| Author Notes: | Patrick Rupprecht, Lennart Aufleger, Simon Heinze, Alexander Magunia, Thomas Ding, Marc Rebholz, Stefano Amberg, Nikola Mollov, Felix Henrich, Maurits W. Haverkort, Christian Ott, and Thomas Pfeifer |
MARC
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| 245 | 1 | 0 | |a Resolving vibrations in a polyatomic molecule with femtometer precision via x-ray spectroscopy |c Patrick Rupprecht, Lennart Aufleger, Simon Heinze, Alexander Magunia, Thomas Ding, Marc Rebholz, Stefano Amberg, Nikola Mollov, Felix Henrich, Maurits W. Haverkort, Christian Ott, and Thomas Pfeifer |
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| 520 | |a We measure molecular vibrations with femtometer precision via resonance energy shifts using time-resolved x-ray absorption spectroscopy. For a demonstration, a Raman process excites the A1g mode in gas-phase SF6 molecules with an amplitude of approximately 50fm, which is probed by a time-delayed soft-x-ray pulse at the sulfur L2,3 edge. Mapping the extremely small measured energy shifts to internuclear distances requires an understanding of the electronic contributions provided by a many-body ab initio simulation. Our study establishes core-level spectroscopy as a precision tool for time-dependent molecular-structure metrology. | ||
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