Azamacrocyclic nickel(II) and copper(II) complexes bearing aryl substituents: synthesis, properties, and crystal structures
A synthetic procedure for preparation of new amphiphilic copper(II) and nickel(II) azamacrocyclic complexes bearing aromatic substituents is developed. The nature of substituents is shown to exert a negligible influence on spectral and electrochemical characteristics of the prepared compounds. The X...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2010
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| In: |
Russian chemical bulletin
Year: 2010, Volume: 59, Issue: 8, Pages: 1572-1581 |
| ISSN: | 1573-9171 |
| DOI: | 10.1007/s11172-010-0280-3 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1007/s11172-010-0280-3
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| Author Notes: | L.V. Tsymbal, I.L. Andriichuk, Ya. D. Lampeka, and H. Pritzkow |
| Summary: | A synthetic procedure for preparation of new amphiphilic copper(II) and nickel(II) azamacrocyclic complexes bearing aromatic substituents is developed. The nature of substituents is shown to exert a negligible influence on spectral and electrochemical characteristics of the prepared compounds. The X-ray diffraction analysis of three copper complexes revealed the formation of the dimers of macrocyclic cations associated by noncovalent interactions, nature of which is determined by the structure of the substituent in the macrocyclic ligand. |
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| Item Description: | Erstmals am 04 January 2011 online veröffentlicht Gesehen am 19.01.2024 |
| Physical Description: | Online Resource |
| ISSN: | 1573-9171 |
| DOI: | 10.1007/s11172-010-0280-3 |