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Zipping up tetraazaperylene: synthesis of tetraazacoronenes via double coupling in the bay positions [data]

Substituted tetraazacoronene fluorophores have been obtained selectively by double Suzuki-Miyaura cross coupling of symmetrically substituted 1,2-bis(pinacolatoboryl)alkenes with a bay-substituted octaazaperopyrenedioxide (OAPPDO). Subsequent Scholl reaction of the dimethoxyphenylated derivative all...

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Bibliographic Details
Main Authors: Eichelmann, Robert (Author) , Rippel, Daniel (Author) , Ballmann, Joachim (Author) , Gade, Lutz H. (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2024-02-20
DOI:10.11588/data/HIERR9
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Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/HIERR9
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/HIERR9
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Author Notes:Robert Eichelmann, Daniel Rippel, Joachim Ballmann, Lutz H. Gade
Description
Summary:Substituted tetraazacoronene fluorophores have been obtained selectively by double Suzuki-Miyaura cross coupling of symmetrically substituted 1,2-bis(pinacolatoboryl)alkenes with a bay-substituted octaazaperopyrenedioxide (OAPPDO). Subsequent Scholl reaction of the dimethoxyphenylated derivative allowed further π-extension of the azaperylene core, yielding a highly redox-active bis(phenanthro)tetraazacoronene.
Item Description:Gefördert durch: German Research Foundation: INST40/575-1FUGG (Justus cluster), German Research Foundation: SFB1249 (TP A2)
Gesehen am 28.02.2024
Physical Description:Online Resource
DOI:10.11588/data/HIERR9

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