Halogenated phenazinothiadiazoles: electron transporting materials [data]

Triisopropylsilyl-(TIPS)-alkynylated phenazinothiadiazoles were prepared by the condensation of halogenated ortho-quinones and TIPS-alkynylated 5,6-diamino-2,1,3-benzothiadiazole with different combinations of halogen substituents. The compounds pack in brickwall motif of head-to-head dimers featuri...

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Main Authors: Zong, Wansheng (Author) , Hippchen, Nikolai (Author) , Dittmar, Benedikt (Author) , Elter, Maximilian (Author) , Ludwig, Philipp (Author) , Rominger, Frank (Author) , Freudenberg, Jan (Author) , Bunz, Uwe H. F. (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2024-01-08
DOI:10.11588/data/PKX5CI
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Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/PKX5CI
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/PKX5CI
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Author Notes:Wansheng Zong, Nikolai Hippchen, Benedikt Dittmar, Maximilian Elter, Philipp Ludwig, Frank Rominger, Jan Freudenberg, Uwe H.F. Bunz
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Summary:Triisopropylsilyl-(TIPS)-alkynylated phenazinothiadiazoles were prepared by the condensation of halogenated ortho-quinones and TIPS-alkynylated 5,6-diamino-2,1,3-benzothiadiazole with different combinations of halogen substituents. The compounds pack in brickwall motif of head-to-head dimers featuring intermolecular S-N contacts and short π-π distances, suggesting their suitability as n-channel materials in organic thin film transistors. The halogenated phenazinothiadiazoles show electron mobilities μmax ranging between 0.14 cm2V-1 s-1 and 0.76 cm2 V-1 s-1.
Item Description:Gefördert durch: Deutsche Forschungsgemeinschaft: INST40/575-1FUGG, Deutsche Forschungsgemeinschaft: SFB 1249
Gesehen am 14.03.2024
Physical Description:Online Resource
DOI:10.11588/data/PKX5CI