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Etheno-bridged azaacene spiro dimers [data]

We present the synthesis of two sets of spiro-connected azaacene dimers. Their geometry and electronic coupling are critically determined by a secondary linker, i.e. an etheno- and an ethano-bridge.The core fragment of the etheno-bridged dimer corresponds to a conformationally locked cis-stilbene. O...

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Bibliographic Details
Main Authors: Ahrens, Lukas (Author) , Rominger, Frank (Author) , Freudenberg, Jan (Author) , Bunz, Uwe H. F. (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2023-05-08
DOI:10.11588/data/L8NDRO
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Forschungsdaten
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Online Access:Resolving-System, kostenfrei, Volltext: https://doi.org/10.11588/data/L8NDRO
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/L8NDRO
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Author Notes:Lukas Ahrens, Frank Rominger, Jan Freudenberg, and Uwe H.F. Bunz
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Summary:We present the synthesis of two sets of spiro-connected azaacene dimers. Their geometry and electronic coupling are critically determined by a secondary linker, i.e. an etheno- and an ethano-bridge.The core fragment of the etheno-bridged dimer corresponds to a conformationally locked cis-stilbene. Optoelectronic properties, single crystal X-ray structures and stability with respect to oxidation of the conjugated and non-conjugated dimers are reported and compared. The conjugated dimers exhibit smaller optical gaps and bathochromically shifted absorption maxima, but are prone to unexpected oxygen addition, dearomatizing one of the azaacene substituents. (2023-05-08)
Item Description:Gefördert durch: Deutsche Forschungsgemeinschaft (DFG): SFB 1249; Studienstiftung des Deutschen Volkes
Gesehen am 02.04.2024
Physical Description:Online Resource
DOI:10.11588/data/L8NDRO

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