Electronic properties of tetraazaperopyrene derivatives on Au(111): energy-level alignment and interfacial band formation [research data]

N-heteropolycyclic aromatic compounds are promising organic electron-transporting semiconductors for applications in field-effect transistors. Here, we investigated the electronic properties of 1,3,8,10-tetraazaperopyrene derivatives adsorbed on Au(111) using a complementary experimental approach, n...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Stein, Arnulf (VerfasserIn) , Rolf, Daniela (VerfasserIn) , Lotze, Christian (VerfasserIn) , Feldmann, Sascha (VerfasserIn) , Gerbert, David (VerfasserIn) , Günther, Benjamin (VerfasserIn) , Jeindl, Andreas (VerfasserIn) , Cartus, Johannes J. (VerfasserIn) , Hofmann, Oliver (VerfasserIn) , Gade, Lutz H. (VerfasserIn) , Franke, Katharina J. (VerfasserIn) , Tegeder, Petra (VerfasserIn)
Dokumenttyp: Datenbank Forschungsdaten
Sprache:Englisch
Veröffentlicht: Heidelberg Universität 2024-04-16
DOI:10.11588/data/0EK2MB
Schlagworte:
Online-Zugang:Resolving-System, kostenfrei, Volltext: https://doi.org/10.11588/data/0EK2MB
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/0EK2MB
Volltext
Verfasserangaben:Arnulf Stein, Daniela Rolf, Christina Lotze, Sascha Feldmann, David Gerbert, Benjamin Günther, Andreas Jeindl, Johannes J. Cartus, Oliver Hofmann, Lutz H. Gade, Kahtarina J. Franke, Petra Tegeder
Beschreibung
Zusammenfassung:N-heteropolycyclic aromatic compounds are promising organic electron-transporting semiconductors for applications in field-effect transistors. Here, we investigated the electronic properties of 1,3,8,10-tetraazaperopyrene derivatives adsorbed on Au(111) using a complementary experimental approach, namely, scanning tunneling spectroscopy and two-photon photoemission combined with state-of-the-art density functional theory. We find signatures of weak physisorption of the molecular layers, such as the absence of charge transfer, a nearly unperturbed surface state, and an intact herringbone reconstruction underneath the molecular layer. Interestingly, molecular states in the energy region of the sp- and d-bands of the Au(111) substrate exhibit hole-like dispersive character. We ascribe this band character to hybridization with the delocalized states of the substrate. We suggest that such bands, which leave the molecular frontier orbitals largely unperturbed, are a promising lead for the design of organic–metal interfaces with a low charge injection barrier.
Beschreibung:Gefördert durch: Deutsche Forschungsgemeinschaft: 281029004 (SFB 1249, Projects A02 and B06); Deutsche Forschungsgemeinschaft: 182087777 (SFB 951) (K.J.F.); International Max Planck Research School “Functional Interfaces in Physics and Chemistry” (D.R.); Austrian Science Fund (FWF): Y1157-N36 “MAP-DESIGN”
Gesehen am 16.04.2024
Beschreibung:Online Resource
DOI:10.11588/data/0EK2MB