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Synthesis of N-thioacetyl gangliosides GM1 and GM3

Reaction of de-N-acetyl gangliosides GM1 (1) and GM3 (2b) with methyl dithioacetate (3) afforded N-thioacetyl GM1 (1c) and N-thioacetyl GM3 (2c) with the oxygen of the acetamido group of N-acetylneuraminic acid residue replaced by sulfur.

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Bibliographic Details
Main Authors: Isecke, Rainer (Author) , Brossmer, Reinhard (Author) , Sonnino, Sandro (Author)
Format: Article (Journal)
Language:English
Published: 7 December 1995
In: Bioorganic & medicinal chemistry letters
Year: 1995, Volume: 5, Issue: 23, Pages: 2805-2808
ISSN:1464-3405
DOI:10.1016/0960-894X(95)00490-K
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/0960-894X(95)00490-K
Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/0960894X9500490K
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Author Notes:Rainer Isecke, Reinhard Brossmer, Sandro Sonnino
Description
Summary:Reaction of de-N-acetyl gangliosides GM1 (1) and GM3 (2b) with methyl dithioacetate (3) afforded N-thioacetyl GM1 (1c) and N-thioacetyl GM3 (2c) with the oxygen of the acetamido group of N-acetylneuraminic acid residue replaced by sulfur.
Item Description:Im Titel sind die Zahlen "1" und "3" tiefgestellt
Elektronische Reproduktion der Druck-Ausgabe 29. März 2000
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Physical Description:Online Resource
ISSN:1464-3405
DOI:10.1016/0960-894X(95)00490-K

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