Gold carbonyl cations and beyond: homoleptic gold(I) complexes with P4 and P4S3 and the half-sandwich cation (Au(C6H6)(CO))+
Oxidation of Au0 with the synergistic Ag+/0.5 I2 system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the perfluoroalkoxyaluminate salt of the [Au(CO)2]+ cation known from superacid chemistry. This [Au(CO)2]+ salt proved to be an excellent ‘naked’ Au+-synthon yielding complex s...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
24 Apr 2024
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| In: |
Chemical communications
Year: 2024, Volume: 60, Issue: 41, Pages: 5403-5406 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D4CC01374C |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1039/D4CC01374C Verlag, kostenfrei, Volltext: https://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc01374c 
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| Author Notes: | Manuel Schmitt, Sarah Nestle, Valentin Radtke, Ingo Krossing |
| Summary: | Oxidation of Au0 with the synergistic Ag+/0.5 I2 system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the perfluoroalkoxyaluminate salt of the [Au(CO)2]+ cation known from superacid chemistry. This [Au(CO)2]+ salt proved to be an excellent ‘naked’ Au+-synthon yielding complex salts with [Au(η2-P4)2]+, [Au(η1-P4S3)2]+ and half-sandwich [Au(η2-C6H6)(CO)]+ cation. |
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| Item Description: | Gesehen am 09.08.2024 Im Titel erscheint die chemische Formel in eckigen Klammern, alle Zahlen sind tiefgestellt, das "+" hochgestellt |
| Physical Description: | Online Resource |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D4CC01374C |