Two dimensional triptycene end-capping and its influence on the self-assembly of quinoxalinophenanthrophenazines [data]

A series of quinoxalinophenanthrophenazines (QPPs) with two-dimensional triptycene end-caps was synthesized from a triphenylene base ortho-diamine. UV/vis spectroscopy suggested the formation of dimers in solution which was further confirmed by MALDI-TIMS-TOF-MS and single crystal X-ray diffraction...

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Main Authors: Roß, Lisa (Author) , Reitemeier, Julius (Author) , Ghalami, Farhad (Author) , Zhang, Wen-Shan (Author) , Gross, Jürgen H. (Author) , Rominger, Frank (Author) , Elbert, Sven (Author) , Schröder, Rasmus R. (Author) , Elstner, Marcus (Author) , Mastalerz, Michael (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2023-03-27
DOI:10.11588/data/W3KWEJ
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Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/W3KWEJ
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/W3KWEJ
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Author Notes:Lisa Roß, Julius Reitemeier, Farhad Ghalami, Wen-Shan Zhang, Jürgen H. Gross, Frank Rominger, Sven M. Elbert, Rasmus Schröder, Marcus Elstner, Michael Mastalerz
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Summary:A series of quinoxalinophenanthrophenazines (QPPs) with two-dimensional triptycene end-caps was synthesized from a triphenylene base ortho-diamine. UV/vis spectroscopy suggested the formation of dimers in solution which was further confirmed by MALDI-TIMS-TOF-MS and single crystal X-ray diffraction analysis. By the latter, the dimer formation attributed to short π-interactions and a perfect shape-match in one case.
Item Description:Gefördert durch: Deutsche Forschungsgemeinschaft: SFB 1249 (TP-A04)
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Physical Description:Online Resource
DOI:10.11588/data/W3KWEJ