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Gold-catalyzed access to pyrrolo- and (aryl)indolo-fused phenazines [data]

Novel fused phenazines were synthesized through a combination of gold-catalyzed hydroamination and cascade cyclization reactions towards azaacenes. In total, 30 new compounds were synthesized and investigated with respect to their structural and optoelectronic properties. In solution, these targets...

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Main Authors: Rudolph, Matthias (Author) , Hüßler, Christopher (Author) , Dietl, Martin C. (Author) , Scherr, Matthias (Author) , Blaum, Immanuel E. (Author) , Stuntebeck, Hanno (Author) , Trogemann, Lea (Author) , Schmidt, Sophia (Author) , Kahle, Justin (Author) , Krämer, Petra (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2025-02-14
DOI:10.11588/DATA/EFKTPA
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Forschungsdaten
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Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/DATA/EFKTPA
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/DATA/EFKTPA
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Author Notes:Matthias Rudolph, Christopher Hüßler, Martin C. Dietl, Matthias Scherr, Immanuel E. Blaum, Hanno Stuntebeck, Lea Trogemann, Sophia Schmidt, Justin Kahle, Petra Krämer, Frank Rominger, A. Stephen K. Hashmi
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Summary:Novel fused phenazines were synthesized through a combination of gold-catalyzed hydroamination and cascade cyclization reactions towards azaacenes. In total, 30 new compounds were synthesized and investigated with respect to their structural and optoelectronic properties. In solution, these targets exhibit strong green to red emission, with quantum yields of up to 60 %. The emission wavelength can be finely adjusted by the choice of solvent due to their solvatochromic behavior, as demonstrated with a representative example.
Item Description:Gefördert duch: Deutsche Forschungsgemeinschaft (DFG): SFB 1249; Hector Fellow Academy: D.120100/20.002; bwHPC: INST 40/575-1 FUGG (JUSTUS 2 cluster)
Gesehen am 17.02.2025
Physical Description:Online Resource
DOI:10.11588/DATA/EFKTPA

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