Gold-catalyzed access to pyrrolo- and (aryl)indolo-fused phenazines [data]

Novel fused phenazines were synthesized through a combination of gold-catalyzed hydroamination and cascade cyclization reactions towards azaacenes. In total, 30 new compounds were synthesized and investigated with respect to their structural and optoelectronic properties. In solution, these targets...

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Hauptverfasser: Rudolph, Matthias (VerfasserIn) , Hüßler, Christopher (VerfasserIn) , Dietl, Martin C. (VerfasserIn) , Scherr, Matthias (VerfasserIn) , Blaum, Immanuel E. (VerfasserIn) , Stuntebeck, Hanno (VerfasserIn) , Trogemann, Lea (VerfasserIn) , Schmidt, Sophia (VerfasserIn) , Kahle, Justin (VerfasserIn) , Krämer, Petra (VerfasserIn) , Rominger, Frank (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Datenbank Forschungsdaten
Sprache:Englisch
Veröffentlicht: Heidelberg Universität 2025-02-14
DOI:10.11588/DATA/EFKTPA
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Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/DATA/EFKTPA
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/DATA/EFKTPA
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Verfasserangaben:Matthias Rudolph, Christopher Hüßler, Martin C. Dietl, Matthias Scherr, Immanuel E. Blaum, Hanno Stuntebeck, Lea Trogemann, Sophia Schmidt, Justin Kahle, Petra Krämer, Frank Rominger, A. Stephen K. Hashmi
Beschreibung
Zusammenfassung:Novel fused phenazines were synthesized through a combination of gold-catalyzed hydroamination and cascade cyclization reactions towards azaacenes. In total, 30 new compounds were synthesized and investigated with respect to their structural and optoelectronic properties. In solution, these targets exhibit strong green to red emission, with quantum yields of up to 60 %. The emission wavelength can be finely adjusted by the choice of solvent due to their solvatochromic behavior, as demonstrated with a representative example.
Beschreibung:Gefördert duch: Deutsche Forschungsgemeinschaft (DFG): SFB 1249; Hector Fellow Academy: D.120100/20.002; bwHPC: INST 40/575-1 FUGG (JUSTUS 2 cluster)
Gesehen am 17.02.2025
Beschreibung:Online Resource
DOI:10.11588/DATA/EFKTPA