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A negatively curved nanographene with four embedded heptagons

Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical proper...

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Bibliographic Details
Main Authors: Elbert, Sven (Author) , Paine, Owen T. A. (Author) , Kirschbaum, Tobias (Author) , Schuldt, Moritz P. (Author) , Weber, Laura (Author) , Rominger, Frank (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: September 27, 2024
In: Journal of the American Chemical Society
Year: 2024, Volume: 146, Issue: 40, Pages: 27324-27334
ISSN:1520-5126
DOI:10.1021/jacs.4c09185
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jacs.4c09185
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Author Notes:Sven M. Elbert, Owen T.A. Paine, Tobias Kirschbaum, Moritz P. Schuldt, Laura Weber, Frank Rominger, and Michael Mastalerz
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Summary:Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C60 and C70 were studied.
Item Description:Gesehen am 26.02.2025
Physical Description:Online Resource
ISSN:1520-5126
DOI:10.1021/jacs.4c09185

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