A negatively curved nanographene with four embedded heptagons
Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical proper...
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| Auteurs principaux: | , , , , , , |
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| Format: | Article (Journal) |
| Langue: | anglais |
| Publié: |
September 27, 2024
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| In: |
Journal of the American Chemical Society
Year: 2024, Volume: 146, Numéro: 40, Pages: 27324-27334 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.4c09185 |
| Accès en ligne: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jacs.4c09185
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| Notes sur l'auteur: | Sven M. Elbert, Owen T.A. Paine, Tobias Kirschbaum, Moritz P. Schuldt, Laura Weber, Frank Rominger, and Michael Mastalerz |
| Résumé: | Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C60 and C70 were studied. |
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| Description: | Gesehen am 26.02.2025 |
| Description matérielle: | Online Resource |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.4c09185 |