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A negatively curved nanographene with four embedded heptagons

Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical proper...

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Hauptverfasser: Elbert, Sven (VerfasserIn) , Paine, Owen T. A. (VerfasserIn) , Kirschbaum, Tobias (VerfasserIn) , Schuldt, Moritz P. (VerfasserIn) , Weber, Laura (VerfasserIn) , Rominger, Frank (VerfasserIn) , Mastalerz, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: September 27, 2024
In: Journal of the American Chemical Society
Year: 2024, Jahrgang: 146, Heft: 40, Pages: 27324-27334
ISSN:1520-5126
DOI:10.1021/jacs.4c09185
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jacs.4c09185
Volltext
Verfasserangaben:Sven M. Elbert, Owen T.A. Paine, Tobias Kirschbaum, Moritz P. Schuldt, Laura Weber, Frank Rominger, and Michael Mastalerz
Beschreibung
Zusammenfassung:Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C60 and C70 were studied.
Beschreibung:Gesehen am 26.02.2025
Beschreibung:Online Resource
ISSN:1520-5126
DOI:10.1021/jacs.4c09185

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