Utilizing enantiomerically pure organic spacers for anion-centred clusters in a hybrid inorganic-organic lead-halide crystal

In this work, we present structural data of the novel, chiral material (S-2AH)4[Pb2Br7]Br obtained from single crystal X-ray diffraction (SCXRD). This quasi-2D material displays anion-centred clusters within its organic layer, without the need for bi-functional spacers. Instead, the structure is bas...

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Bibliographic Details
Main Authors: Heindl, Markus W. (Author) , Ballmann, Joachim (Author) , Deschler, Felix (Author)
Format: Article (Journal)
Language:English
Published: 19 Jun 2025
In: Chemical communications
Year: 2025, Volume: 61, Issue: 58, Pages: 10855-10858
ISSN:1364-548X
DOI:10.1039/D5CC01101A
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.1039/D5CC01101A
Verlag, kostenfrei, Volltext: https://pubs.rsc.org/en/content/articlelanding/2025/cc/d5cc01101a
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Author Notes:Markus W. Heindl, Joachim Ballmann and Felix Deschler
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Summary:In this work, we present structural data of the novel, chiral material (S-2AH)4[Pb2Br7]Br obtained from single crystal X-ray diffraction (SCXRD). This quasi-2D material displays anion-centred clusters within its organic layer, without the need for bi-functional spacers. Instead, the structure is based on the steric properties of the used enantiomerically pure precursors.
Item Description:Zuerst veröffentlicht: 19. Juni 2025
Gesehen am 15.10.2025
Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/D5CC01101A