Utilizing enantiomerically pure organic spacers for anion-centred clusters in a hybrid inorganic-organic lead-halide crystal
In this work, we present structural data of the novel, chiral material (S-2AH)4[Pb2Br7]Br obtained from single crystal X-ray diffraction (SCXRD). This quasi-2D material displays anion-centred clusters within its organic layer, without the need for bi-functional spacers. Instead, the structure is bas...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
19 Jun 2025
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| In: |
Chemical communications
Year: 2025, Volume: 61, Issue: 58, Pages: 10855-10858 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D5CC01101A |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1039/D5CC01101A Verlag, kostenfrei, Volltext: https://pubs.rsc.org/en/content/articlelanding/2025/cc/d5cc01101a |
| Author Notes: | Markus W. Heindl, Joachim Ballmann and Felix Deschler |
| Summary: | In this work, we present structural data of the novel, chiral material (S-2AH)4[Pb2Br7]Br obtained from single crystal X-ray diffraction (SCXRD). This quasi-2D material displays anion-centred clusters within its organic layer, without the need for bi-functional spacers. Instead, the structure is based on the steric properties of the used enantiomerically pure precursors. |
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| Item Description: | Zuerst veröffentlicht: 19. Juni 2025 Gesehen am 15.10.2025 |
| Physical Description: | Online Resource |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D5CC01101A |