(Hetero)anilines from dinitrogen via nucleophilic aromatic substitution at tungsten nitrido complexes
A protocol for the arylation of both N atoms in dinitrogen is presented. This protocol relies on the use of tungsten pincer complexes to split N2 and generate tungsten nitrides, which were shown to undergo nucleophilic aromatic substitution (SNAr) reactions with electron-deficient aryl chlorides. St...
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| Main Authors: | , |
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| Format: | Article (Journal) Editorial |
| Language: | English |
| Published: |
July 11, 2025
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| In: |
Journal of the American Chemical Society
Year: 2025, Volume: 147, Issue: 29, Pages: 25123-25128 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.5c06407 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1021/jacs.5c06407
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| Author Notes: | Lukas Eberle and Joachim Ballmann |
| Summary: | A protocol for the arylation of both N atoms in dinitrogen is presented. This protocol relies on the use of tungsten pincer complexes to split N2 and generate tungsten nitrides, which were shown to undergo nucleophilic aromatic substitution (SNAr) reactions with electron-deficient aryl chlorides. Starting from (15N)2, this two-step process was exploited for the preparation of different 15N-labeled aryl amines. |
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| Item Description: | Gesehen am 13.11.2025 |
| Physical Description: | Online Resource |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.5c06407 |