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Silver-catalyzed cascade approach to access fused pyrazolo-naphthyridine and -isoquinoline backbones and investigation of their photophysical properties

We describe a novel approach for synthesizing diverse fused heterocyclic compounds by utilizing a sequential silver(I) catalyzed reaction between readily obtainable N-amidonaphthyridin ylide and dialkyl acetylenedicarboxylates. This method provides an efficient approach for the selective synthesis o...

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Main Authors: Mobarakeh, Fatemeh Abdiyan (Author) , Rezaei-Gohar, Mohammad (Author) , Amiri, Kamran (Author) , Bijanzadeh, Hamid Reza (Author) , Rominger, Frank (Author) , Balalaie, Saeed (Author)
Format: Article (Journal)
Language:English
Published: April 4, 2025
In: ACS omega
Year: 2025, Volume: 10, Issue: 14, Pages: 14063-14074
ISSN:2470-1343
DOI:10.1021/acsomega.4c11109
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acsomega.4c11109
Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/acsomega.4c11109
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Author Notes:Fatemeh Abdiyan Mobarakeh, Mohammad Rezaei-Gohar, Kamran Amiri, Hamid Reza Bijanzadeh, Frank Rominger, and Saeed Balalaie
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Summary:We describe a novel approach for synthesizing diverse fused heterocyclic compounds by utilizing a sequential silver(I) catalyzed reaction between readily obtainable N-amidonaphthyridin ylide and dialkyl acetylenedicarboxylates. This method provides an efficient approach for the selective synthesis of tetracyclic ring-fused 1,6-naphthyridine and isoquinoline derivatives, offering exceptional structural diversity. In addition, the title compounds constitute an interesting class of luminophores with tunable emission solvatochromicity.
Item Description:Veröffentlicht: 04. April 2025
Gesehen am 03.12.2025
Physical Description:Online Resource
ISSN:2470-1343
DOI:10.1021/acsomega.4c11109

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