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Targeted synthesis of a positional isomer of aromatic N-methyl N-confused corrole and its organocopper(III) complex

We report the synthesis, spectroscopic analyses and solid-state structural evidence of an unprecedented positional isomer of aromatic [18] N-confused corrole exhibiting vis-NIR absorption. Copper metalation led to an organo-copper(III) complex with preserved aromaticity.

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Bibliographic Details
Main Authors: Panua, Anirban (Author) , Velmurugan, Gunasekaran (Author) , Comba, Peter (Author) , Rath, Harapriya (Author)
Format: Article (Journal)
Language:English
Published: 18 November 2025
In: Chemical communications
Year: 2025, Volume: 61, Issue: 89, Pages: 17436-17439
ISSN:1364-548X
DOI:10.1039/D5CC05372B
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D5CC05372B
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2025/cc/d5cc05372b
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Author Notes:Anirban Panua, Gunasekaran Velmurugan, Peter Comba and Harapriya Rath
Description
Summary:We report the synthesis, spectroscopic analyses and solid-state structural evidence of an unprecedented positional isomer of aromatic [18] N-confused corrole exhibiting vis-NIR absorption. Copper metalation led to an organo-copper(III) complex with preserved aromaticity.
Item Description:Erstveröffentlichung: 6. Oktober 2025
Gesehen am 02.02.2026
Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/D5CC05372B

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