3D digital light processing of redox-active polymers for electrochemical applications

A novel approach for the 3D printing of electrochemically switchable conducting polymers by combining Digital Light Processing (DLP) with the redox-activity of carbazole-based polymer materials is presented. Complex 2D and 3D architectures are accessible by fast and versatile processing using a nove...

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Auteurs principaux: Delavier, Christian (Auteur) , Bechtold, Svenja (Auteur) , Dodds, Marcus (Auteur) , Blasco, Eva (Auteur) , Ludwigs, Sabine (Auteur)
Format: Article (Journal)
Langue:anglais
Publié: 12 November 2025
Édition:Online version of record before inclusion in an issue
In: Advanced functional materials
Year: 2025, Pages: 1-12
ISSN:1616-3028
DOI:10.1002/adfm.202518546
Accès en ligne:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/adfm.202518546
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adfm.202518546
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Notes sur l'auteur:Christian Delavier, Svenja Bechtold, Marcus H. Dodds, Eva Blasco, and Sabine Ludwigs
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Résumé:A novel approach for the 3D printing of electrochemically switchable conducting polymers by combining Digital Light Processing (DLP) with the redox-activity of carbazole-based polymer materials is presented. Complex 2D and 3D architectures are accessible by fast and versatile processing using a novel ink formulation. The printed polymer materials not only retain their redox-active response, but enable post-printing electrochemical manipulation throughout the printed structure, here demonstrated by elongation of the redox system via electrochemical crosslinking. Cyclic voltammetry coupled with in-situ spectroscopy provides insights into these redox processes and the optical changes during electrochemical doping of the 3D printed structures. Highlights include pixel-level electrochemical control via a chessboard design and color front visualization through a pyramid architecture. The integration of high-resolution 3D printing with redox-active materials opens new avenues in a wide range of applications in 3D printed (opto)electronics and switchable electrochemical devices.
Description:Gesehen am 17.02.2026
Description matérielle:Online Resource
ISSN:1616-3028
DOI:10.1002/adfm.202518546