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Metal-free C–C coupling reactions with tetraguanidino-functionalized pyridines and light

Herein we report on metal-free C–C coupling reactions mediated by the pyridine derivative 2,3,6,7-tetrakis(tetramethylguanidino)pyridine under the action of visible light. The rate-determining step is the homolytic N–C bond cleavage of the initially formed N-alkyl pyridinium ion upon excitation with...

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Bibliographic Details
Main Authors: Stang, Simone (Author) , Kaifer, Elisabeth (Author) , Himmel, Hans-Jörg (Author)
Format: Article (Journal)
Language:English
Published: March 27, 2014
In: Chemistry - a European journal
Year: 2014, Volume: 20, Issue: 18, Pages: 5288-5297
ISSN:1521-3765
DOI:10.1002/chem.201304987
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201304987
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201304987
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Author Notes:Simone Stang, Elisabeth Kaifer, and Hans-Jörg Himmel
Description
Summary:Herein we report on metal-free C–C coupling reactions mediated by the pyridine derivative 2,3,6,7-tetrakis(tetramethylguanidino)pyridine under the action of visible light. The rate-determining step is the homolytic N–C bond cleavage of the initially formed N-alkyl pyridinium ion upon excitation with visible light.
Item Description:Gesehen am 31.07.2020
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201304987

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