Metal-free C–C coupling reactions with tetraguanidino-functionalized pyridines and light
Herein we report on metal-free C–C coupling reactions mediated by the pyridine derivative 2,3,6,7-tetrakis(tetramethylguanidino)pyridine under the action of visible light. The rate-determining step is the homolytic N–C bond cleavage of the initially formed N-alkyl pyridinium ion upon excitation with...
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 27, 2014
|
| In: |
Chemistry - a European journal
Year: 2014, Jahrgang: 20, Heft: 18, Pages: 5288-5297 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201304987 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201304987 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201304987 
|
| Verfasserangaben: | Simone Stang, Elisabeth Kaifer, and Hans-Jörg Himmel |
| Zusammenfassung: | Herein we report on metal-free C–C coupling reactions mediated by the pyridine derivative 2,3,6,7-tetrakis(tetramethylguanidino)pyridine under the action of visible light. The rate-determining step is the homolytic N–C bond cleavage of the initially formed N-alkyl pyridinium ion upon excitation with visible light. |
|---|---|
| Beschreibung: | Gesehen am 31.07.2020 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201304987 |